{"id":575,"date":"2018-11-28T12:18:48","date_gmt":"2018-11-28T10:18:48","guid":{"rendered":"https:\/\/nicl.it\/new\/?p=575"},"modified":"2023-08-15T16:54:18","modified_gmt":"2023-08-15T14:54:18","slug":"validation-of-the-kinetics-of-the-hydrogen-peroxide-propene-oxide-process-in-a-dynamic-continuous-stirred-tank-reactor","status":"publish","type":"post","link":"https:\/\/nicl.it\/new\/validation-of-the-kinetics-of-the-hydrogen-peroxide-propene-oxide-process-in-a-dynamic-continuous-stirred-tank-reactor","title":{"rendered":"Validation of the kinetics of the hydrogen peroxide propene oxide process in a dynamic continuous stirred tank reactor"},"content":{"rendered":"<p>Russo, V., Santacesaria, E., Tesser, R., Turco, R., Vitiello, R., Di Serio, M.<\/p>\n<div class=\"article_header-cite-this\"><span class=\"cit-title\"><i>Ind. Eng. Chem. Res.<\/i><\/span>\u00a0<span class=\"cit-year-info\">2018<\/span><span class=\"cit-volume\">, 57<\/span><span class=\"cit-issue\">, 48<\/span><span class=\"cit-pageRange\">, 16201\u201316208 <\/span><span class=\"pub-date epub-date\">Publication Date<\/span><span class=\"date-separator\">:<\/span><span class=\"pub-date-value\">November 16, 2018<\/span><\/div>\n<div class=\"article_header-doiurl\"><a title=\"DOI URL\" href=\"https:\/\/doi.org\/10.1021\/acs.iecr.8b03233\">https:\/\/doi.org\/10.1021\/acs.iecr.8b03233<\/a><\/div>\n<p>&nbsp;<\/p>\n<div class=\"article_abstract\">\n<div class=\"container container_scaled-down\">\n<div class=\"row\">\n<div class=\"col-xs-12\">\n<div id=\"abstractBox\" class=\"article_abstract-content hlFld-Abstract\">\n<p><strong>Abstract<\/strong><\/p>\n<p class=\"articleBody_abstractText\">A continuous hydrogen peroxide propene oxide (HPPO) lab-scale pilot plant was designed and tested for the production of propene oxide via HPPO process. The plant was equipped with a continuous stirred tank reactor, able to work under nitrogen pressure with liquid propene. Attention was paid to the feed system and the plant control, the lab-scale pilot plant being completely automated. Hydraulic tests were performed to check the performance of the plant; a fluid-dynamic characterization was conducted to evaluate the residence time distribution. Propene oxide synthesis experiments were performed to evaluate both hydrogen peroxide conversion and propene oxide selectivity. The collected data were interpreted with a recently published kinetics, validating the developed model, obtaining satisfactory results, also in simulating the start-up transient state of the reactor. The model can be considered of high utility in designing and optimizing HPPO process, to achieve high reactant conversions and propene oxide yields.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"container container_scaled-down article_citedby-section-container\">\n<div class=\"row\">\n<div class=\"col-xs-12\">\n<div class=\"article_content-table\">\n<div class=\"article_content-row\">\n<div class=\"article_content-left article_content-left-fullwidth ui-resizable\">\n<div class=\"articleCitedByDropzone\" data-pb-dropzone=\"articleCitedByDropzone\">\n<div class=\"cited-by\">\n<div class=\"article_content-header cited-content_header\">\n<div class=\"article_content-header-row\">\n<div class=\"article_content-title\"><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>Russo, V., Santacesaria, E., Tesser, R., Turco, R., Vitiello, R., Di Serio, M. Ind. Eng. Chem. Res.\u00a02018, 57, 48, 16201\u201316208 Publication Date:November 16, 2018 https:\/\/doi.org\/10.1021\/acs.iecr.8b03233 &nbsp; Abstract A continuous hydrogen peroxide propene oxide (HPPO) lab-scale pilot plant was designed and tested for the production of propene oxide via HPPO process. The plant was equipped with [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":2038,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[26,17],"tags":[],"class_list":["post-575","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-epoxidation_olefins","category-publications"],"acf":[],"_links":{"self":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/575","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/comments?post=575"}],"version-history":[{"count":3,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/575\/revisions"}],"predecessor-version":[{"id":2039,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/575\/revisions\/2039"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media\/2038"}],"wp:attachment":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media?parent=575"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/categories?post=575"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/tags?post=575"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}