{"id":2568,"date":"2000-04-12T11:27:36","date_gmt":"2000-04-12T09:27:36","guid":{"rendered":"https:\/\/nicl.it\/new\/?p=2568"},"modified":"2026-04-12T11:31:27","modified_gmt":"2026-04-12T09:31:27","slug":"characteristics-of-block-copolymers-of-methyl-oxirane-and-oxirane-derivatives-of-2-ethylhexanol-as-obtained-with-koh-and-dimetalcyanide-type-catalys","status":"publish","type":"post","link":"https:\/\/nicl.it\/new\/characteristics-of-block-copolymers-of-methyl-oxirane-and-oxirane-derivatives-of-2-ethylhexanol-as-obtained-with-koh-and-dimetalcyanide-type-catalys","title":{"rendered":"Characteristics of Block Copolymers of Methyl Oxirane and Oxirane Derivatives of 2-Ethylhexanol as Obtained with KOH and Dimetalcyanide Type Catalys"},"content":{"rendered":"<p>Wies\u0142aw Hreczuch, Arkadiusz Chrusciel, Karolina Dabrowska, Martino Di Serio, Sun Yongqiang<\/p>\n<p><a href=\"https:\/\/www.degruyterbrill.com\/document\/doi\/10.3139\/113.110431\/html\">Tenside Surf. Det. 53 (2016) 3\u00a0\u00a0<\/a><\/p>\n<p>Abstract<\/p>\n<p>Two series of block copolymers of methyloxirane and oxirane, derivatives of 2-ethylhexanol, were obtained with the use of KOH as a conventional homogeneous alkaline catalyst and a co<br \/>\nordinative dimetalcyanide catalyst (DMC), respectively. The DMC type catalyst showed much higher kinetic activities and its reac tion exhibited a narrower distribution of homologues, as com<br \/>\npared with those obtained in the presence of KOH. The thermo gravimetric technique was proposed for the characterization of the fractional content of products. The pluming phenomenon<br \/>\nand VOCs content were discussed as a practical aspect of the differences in fractional compositions of the products examined.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Wies\u0142aw Hreczuch, Arkadiusz Chrusciel, Karolina Dabrowska, Martino Di Serio, Sun Yongqiang Tenside Surf. Det. 53 (2016) 3\u00a0\u00a0 Abstract Two series of block copolymers of methyloxirane and oxirane, derivatives of 2-ethylhexanol, were obtained with the use of KOH as a conventional homogeneous alkaline catalyst and a co ordinative dimetalcyanide catalyst (DMC), respectively. The DMC type catalyst [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":2569,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[25,17],"tags":[],"class_list":["post-2568","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-alkoxylation-reactions","category-publications"],"acf":[],"_links":{"self":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/2568","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/comments?post=2568"}],"version-history":[{"count":1,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/2568\/revisions"}],"predecessor-version":[{"id":2570,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/2568\/revisions\/2570"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media\/2569"}],"wp:attachment":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media?parent=2568"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/categories?post=2568"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/tags?post=2568"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}