{"id":2050,"date":"2017-08-26T20:24:19","date_gmt":"2017-08-26T18:24:19","guid":{"rendered":"https:\/\/nicl.it\/new\/?p=2050"},"modified":"2023-08-26T20:28:08","modified_gmt":"2023-08-26T18:28:08","slug":"synthesis-of-biolubricant-basestocks-from-epoxidized-soybean-oil-2","status":"publish","type":"post","link":"https:\/\/nicl.it\/new\/synthesis-of-biolubricant-basestocks-from-epoxidized-soybean-oil-2","title":{"rendered":"Synthesis of Biolubricant Basestocks from Epoxidized Soybean Oil"},"content":{"rendered":"<p>Rosa Turco, Riccardo Tesser, Rosa Vitiello, Vincenzo Russo, Salvatore Andini and Martino Di Serio<\/p>\n<p><em>Catalysts<\/em>\u00a0<b>2017<\/b>,\u00a0<em>7<\/em>(10), 309;\u00a0<a href=\"https:\/\/doi.org\/10.3390\/catal7100309\">https:\/\/doi.org\/10.3390\/catal7100309<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>Abstract<\/p>\n<p>This work deals with the preparation of biolubricant basestocks through the ring-opening reaction of epoxidized soybean oil (ESO) by alcohols in presence of solid acid catalysts (SAC-13 resin). To this end, different experimental runs were carried out in a lab-scale reactor, analyzing the effect of the alcohol (methanol, ethanol, 2-propanol, 2-butanol), catalyst mass loading (from 1 to 10 wt % with respect to the oil mass) and operating temperature (60\u201390 \u00b0C). The main focus of investigation was oxirane conversion. The study was complemented by FT-IR,\u00a0<sup>1<\/sup>H NMR and kinematic viscosity characterization of the different products of the ring-opening reaction. Experimental conversion data were fitted through a suitable kinetic model. Values of the best-fitting parameters in terms of rate constant, activation energy and catalyst reaction order were obtained, and were potentially useful for the design of an industrial process.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Rosa Turco, Riccardo Tesser, Rosa Vitiello, Vincenzo Russo, Salvatore Andini and Martino Di Serio Catalysts\u00a02017,\u00a07(10), 309;\u00a0https:\/\/doi.org\/10.3390\/catal7100309 &nbsp; Abstract This work deals with the preparation of biolubricant basestocks through the ring-opening reaction of epoxidized soybean oil (ESO) by alcohols in presence of solid acid catalysts (SAC-13 resin). To this end, different experimental runs were carried out [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":946,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[27,17],"tags":[],"class_list":["post-2050","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-biolubricants","category-publications"],"acf":[],"_links":{"self":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/2050","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/comments?post=2050"}],"version-history":[{"count":1,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/2050\/revisions"}],"predecessor-version":[{"id":2051,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/2050\/revisions\/2051"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media\/946"}],"wp:attachment":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media?parent=2050"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/categories?post=2050"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/tags?post=2050"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}