{"id":1835,"date":"2022-11-12T15:36:27","date_gmt":"2022-11-12T13:36:27","guid":{"rendered":"https:\/\/nicl.it\/new\/?p=1835"},"modified":"2022-11-12T15:39:17","modified_gmt":"2022-11-12T13:39:17","slug":"water-reservoir-properties-dependent-on-packing-modes-of-niii3l6-cages","status":"publish","type":"post","link":"https:\/\/nicl.it\/new\/water-reservoir-properties-dependent-on-packing-modes-of-niii3l6-cages","title":{"rendered":"Water-reservoir properties dependent on packing modes of [Ni(II)3L6] cages"},"content":{"rendered":"<p>Geonwoo Gwak, Seonghyeon An, Dongwon Kim, Martino Di Serio, and Ok-Sang Jung<\/p>\n<p><i><strong>New J. Chem.<\/strong><\/i>, 2022, Accepted Manuscript<\/p>\n<p>DOI<a class=\"text--small\" title=\"Link to landing page via DOI\" href=\"https:\/\/doi.org\/10.1039\/D2NJ04751A\">https:\/\/doi.org\/10.1039\/D2NJ04751A<\/a><\/p>\n<p>Self-assembly of NiX2 (X = Br- and Cl-) with bidentate dialkyl(3-pyridyl)silane ligands (dialkyl- = (3,3,3-trifluoropropyl)methyl-(L1), = cyclohexylmethyl- (L2), = ethylmethyl- (L3)) gives rise to stable crystals consisting of the Ni3L6 cage motif. Each cage exists as a discrete species encapsulating two halide anions, but its packing mode determines its guest-accessible void volume. The void volume acts as a sustainable reservoir for reversible adsorption\/desorption of water.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Geonwoo Gwak, Seonghyeon An, Dongwon Kim, Martino Di Serio, and Ok-Sang Jung New J. Chem., 2022, Accepted Manuscript DOIhttps:\/\/doi.org\/10.1039\/D2NJ04751A Self-assembly of NiX2 (X = Br- and Cl-) with bidentate dialkyl(3-pyridyl)silane ligands (dialkyl- = (3,3,3-trifluoropropyl)methyl-(L1), = cyclohexylmethyl- (L2), = ethylmethyl- (L3)) gives rise to stable crystals consisting of the Ni3L6 cage motif. Each cage exists as [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":1836,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[4,17],"tags":[],"class_list":["post-1835","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-homepage","category-publications"],"acf":[],"_links":{"self":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/1835","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/comments?post=1835"}],"version-history":[{"count":3,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/1835\/revisions"}],"predecessor-version":[{"id":1839,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/1835\/revisions\/1839"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media\/1836"}],"wp:attachment":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media?parent=1835"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/categories?post=1835"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/tags?post=1835"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}