{"id":1094,"date":"2000-02-07T16:42:19","date_gmt":"2000-02-07T14:42:19","guid":{"rendered":"https:\/\/nicl.it\/new\/?p=1094"},"modified":"2021-11-05T18:39:58","modified_gmt":"2021-11-05T16:39:58","slug":"description-of-the-liquid-liquid-equilibrium-in-binary-and-multicomponent-cfc-lubricating-oil-mixtures-by-means-of-an-extended-flory-huggins-model","status":"publish","type":"post","link":"https:\/\/nicl.it\/new\/description-of-the-liquid-liquid-equilibrium-in-binary-and-multicomponent-cfc-lubricating-oil-mixtures-by-means-of-an-extended-flory-huggins-model","title":{"rendered":"Description of the liquid\u2013liquid equilibrium in binary and multicomponent CFC\/lubricating oil mixtures by means of an extended Flory\u2013Huggins model"},"content":{"rendered":"<p><a href=\"https:\/\/doi.org\/10.1016\/S0022-1139(99)00255-9\">Description of the liquid\u2013liquid equilibrium in binary and multicomponent CFC\/lubricating oil mixtures by means of an extended Flory\u2013Huggins model<\/a><\/p>\n<p>Musso, E.; Tesser, R.; Basile, G.; Di Serio, M. Santacesaria, E.<\/p>\n<p>Journal of Fluorine Chemistry 103 (2000) 41-51<\/p>\n<p><a href=\"https:\/\/doi.org\/10.1016\/S0022-1139(99)00255-9\">https:\/\/doi.org\/10.1016\/S0022-1139(99)00255-9<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>Abstract<\/p>\n<p>An extended Flory-Huggins model has been developed and used to interpret liquid-liquid phase diagrams related to binary mixtures of CFC-lubricating oil for which miscibility gaps of UCST, LCST and hourglass type are present. Some liquid-liquid equilibrium measurements have been carried out for the fluorinated compounds R134a, R125, R143a, and R32 in mixtures with polyester-based lubricating oils (PES), pentaerythritol tetraheptanoate (PTE) and trimethylolpropane triheptanoate (TTE). The extended Flory-Huggins model has been applied in the simultaneous description of the liquid-liquid and vapor-liquid phase equilibrium using the same set of adjustable parameters. On the basis of the results obtained in fitting binary systems, a predictive approach has been developed for the description of a miscibility gap related to a mixture formed by two or more halogenated compounds with a lubricating oil<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Description of the liquid\u2013liquid equilibrium in binary and multicomponent CFC\/lubricating oil mixtures by means of an extended Flory\u2013Huggins model Musso, E.; Tesser, R.; Basile, G.; Di Serio, M. Santacesaria, E. Journal of Fluorine Chemistry 103 (2000) 41-51 https:\/\/doi.org\/10.1016\/S0022-1139(99)00255-9 &nbsp; Abstract An extended Flory-Huggins model has been developed and used to interpret liquid-liquid phase diagrams related [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":1095,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[17],"tags":[],"class_list":["post-1094","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-publications"],"acf":[],"_links":{"self":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/1094","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/comments?post=1094"}],"version-history":[{"count":1,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/1094\/revisions"}],"predecessor-version":[{"id":1096,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/1094\/revisions\/1096"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media\/1095"}],"wp:attachment":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media?parent=1094"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/categories?post=1094"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/tags?post=1094"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}