{"id":103,"date":"2020-05-10T09:27:47","date_gmt":"2020-05-10T07:27:47","guid":{"rendered":"https:\/\/nicl.it\/new\/?p=103"},"modified":"2020-07-31T17:52:57","modified_gmt":"2020-07-31T15:52:57","slug":"production-of-epichlorohydrin","status":"publish","type":"post","link":"https:\/\/nicl.it\/new\/production-of-epichlorohydrin","title":{"rendered":"Production of epichlorohydrin"},"content":{"rendered":"<h3>EPICHLOROHYDRIN PRODUCTION<\/h3>\n<p>Biodiesel is a mixture of fatty acids methyl esters (FAMEs) obtained by transesterification of triglycerides (oils or fats) with methanol:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignleft wp-image-106 size-full\" src=\"https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI1_IMG.jpg\" alt=\"\" width=\"329\" height=\"130\" srcset=\"https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI1_IMG.jpg 329w, https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI1_IMG-150x59.jpg 150w, https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI1_IMG-300x119.jpg 300w\" sizes=\"auto, (max-width: 329px) 100vw, 329px\" \/>The reaction also produces glycerin (around 10 Kg of glycerin per 100 Kg of biodiesel). The strong increase in biodiesel production (from 2 million ton in 2004 to 16 million ton in 2009) has produced a glycerin glut with a consequent\u00a0<b><a href=\"https:\/\/nicl.it\/new\/epychlorohydrin-production\/\">price decreases<\/a><\/b>. Because its low price and its reactivity, the glycerin is now considered as an intersting building block by industry for production of\u00a0<b><a href=\"https:\/\/nicl.it\/new\/possible-uses-of-glycerin\/\">several chemical products<\/a><\/b>.<\/p>\n<p>Among the different possible use of glycerol, NICL has studied the\u00a0<b><a href=\"https:\/\/nicl.it\/new\/chlorination-of-glycerol\/\">chlorination of glycerol<\/a><\/b>\u00a0to produce the dichlorohydrin wich is used then to produce\u00a0<b><a href=\"https:\/\/nicl.it\/new\/epichlorhydrin\/\">epichlohydrin<\/a><\/b>.<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignleft wp-image-109 size-full\" src=\"https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI4_IMG.jpg\" alt=\"\" width=\"199\" height=\"125\" srcset=\"https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI4_IMG.jpg 199w, https:\/\/nicl.it\/new\/wp-content\/uploads\/2019\/05\/EPI4_IMG-150x94.jpg 150w\" sizes=\"auto, (max-width: 199px) 100vw, 199px\" \/>This process has been proposed as substituted of the\u00a0<b><a href=\"https:\/\/nicl.it\/new\/chlorination-of-propylene\/\">propylene chlorination<\/a><\/b>\u00a0classical route .<br \/>\nThe production of epichlorohydrin from glycerol is more convinient from\u00a0<b><a href=\"https:\/\/nicl.it\/new\/environmental-advantages\/\">enviromental<\/a>,<\/b><b><a href=\"https:\/\/nicl.it\/new\/technical-advantages\/\">technical<\/a><\/b>\u00a0and\u00a0<b><a href=\"https:\/\/nicl.it\/new\/economical-advantages\/\">economic<\/a><\/b>\u00a0points of view than the classical route.<br \/>\nNICL is among\u00a0<b><a href=\"https:\/\/nicl.it\/new\/epi10\/\">the pioneers of Glycerin Chlorination Technology<\/a><\/b>\u00a0and some of the results of its research activities done in collaboration with industrial parteners (ASER, Eurochem Eng., CONSER) have been reported in patent applications and scientific publications.<\/p>\n<p>&nbsp;<\/p>\n<h3>Publications<\/h3>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.iecr.5b03765\" target=\"_blank\" rel=\"noopener noreferrer\">New production processes of dichlorohydrins from glycerol using acyl chlorides as catalysts or reactants.<\/a><\/b>\u00a0R. Vitiello, R. Tesser, E. Santacesaria, M. Di Serio. Ind. Eng. Chem. Res., Just Accepted Manuscript DOI: 10.1021\/acs.iecr.5b03765<\/li>\n<li><b><a href=\"http:\/\/dx.doi.org\/10.1016\/S1872-2067(14)60069-3\" target=\"_blank\" rel=\"noopener noreferrer\">Glycerol chlorination in a gas-liquid semibatch reactor: New catalysts for chlorohydrin production<\/a>\u00a0<\/b><b><\/b>R Vitiello, V Russo, R Turco, R Tesser, M Di Serio, E Santacesaria. Chinese Journal of Catalysis 35 (5) (2014) 663-66<\/li>\n<li><b><a href=\"http:\/\/dx.doi.org\/10.1021\/ie403268b\" target=\"_blank\" rel=\"noopener noreferrer\">Chemical and Technical Aspects of the Synthesis of Chlorohydrins from Glycerol.<\/a>\u00a0<\/b><b><\/b>E Santacesaria, R Vitiello, R Tesser, V Russo, R Turco, M Di Serio. Industrial &amp; Engineering Chemistry Research 53 (22) (2014) 8939-8962<\/li>\n<li><b><a href=\"http:\/\/dx.doi.org\/10.1021\/ie201629z\" target=\"_blank\" rel=\"noopener noreferrer\">Glycerol Chlorination in Gas\u0001Liquid Semibatch Reactor: An Alternative Route for Chlorohydrins Production.<\/a>\u00a0<\/b><b><\/b>R. Tesser, M. Di Serio, R. Vitiello, V. Russo, E. Ranieri, E. Speranza, E. Santacesaria. Ind. Eng. Chem. Res. (2012) 51, 8768-8776<\/li>\n<li><b><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ie900650x?prevSearch=di%2Bserio&amp;searchHistoryKey=\" target=\"_blank\" rel=\"noopener noreferrer\">New process for producing epichlorohydrin via glycerol chlorination.<\/a>\u00a0<\/b><b><\/b>Santacesaria, E.; Tesser, R.; Di Serio, M.; Casale, L.; Verde, D. Industrial &amp; Engineering Chemistry Research (2010), 49(3), 964-970.<\/li>\n<\/ul>\n<h3>Patents<\/h3>\n<p>&nbsp;<\/p>\n<ul>\n<li><a href=\"http:\/\/Gli esami del prof. Di Serio si terrano il 10 Settembre 2020 presso il Dipartimento di Scienze Chimiche dalle ore 10.00.\u00a0 L'aula sar\u00e0 comunicata in seguito. Prenotarsi via SEGREPASS 7 giorni prima Per l'esame di Chimica Industriale I sar\u00e0 organizzata la prova scritta in presenza il 3 Settembre dalle ore 9.00.\u00a0 L'aula sar\u00e0 comunicata in seguito. Prenotarsi con una mail entro il 27 Agosto all'indirizzo v.russo@unina.it Le modalit\u00e0 di esame in accordo con le procedure di sicurezza previste sono riportate nell'allegato.\"><b>Process for the production of chlorohydrins from glycerol and acyl chlorides<\/b><\/a>\u00a0 Santacesaria Elio; Di Serio, Martino; Tesser, Riccardo; Vitiello, Rosa (Conser SpA; Eurochem Enginnering) PCT Int. Apl. (2016) WO 2016009344 (A1)<\/li>\n<li><b><a href=\"http:\/\/worldwide.espacenet.com\/publicationDetails\/biblio?DB=EPODOC&amp;II=1&amp;ND=3&amp;adjacent=true&amp;locale=en_EP&amp;FT=D&amp;date=20150312&amp;CC=WO&amp;NR=2015033365A1&amp;KC=A1\" target=\"_blank\" rel=\"noopener noreferrer\">Process for the production of dichlorydrins.<\/a>\u00a0<\/b>Santacesaria, Elio; Tesser, Riccardo; Vitiello, Rosa; Di Serio, Martino. (Eurochem Engineering srl, Conser spa) PCT Int. Appl. (2015) WO 2015033365 (A1)<\/li>\n<li><b><a href=\"http:\/\/worldwide.espacenet.com\/publicationDetails\/biblio?DB=EPODOC&amp;II=0&amp;ND=3&amp;adjacent=true&amp;locale=en_EP&amp;FT=D&amp;date=20081106&amp;CC=WO&amp;NR=2008132770A1&amp;KC=A1\" target=\"_blank\" rel=\"noopener noreferrer\">Process for monochlorohydrins production from glycerol and hydrochloric acid.\u00a0<\/a><\/b>Santacesaria, Elio; Di Serio, Martino; Tesser, Riccardo. (Eurochem Engineering srl) PCT Int. Appl. (2008) WO 2008132770 (A1)<\/li>\n<li><b><a href=\"http:\/\/worldwide.espacenet.com\/publicationDetails\/biblio?DB=EPODOC&amp;II=11&amp;ND=3&amp;adjacent=true&amp;locale=en_EP&amp;FT=D&amp;date=20090305&amp;CC=US&amp;NR=2009062574A1&amp;KC=A1\" target=\"_blank\" rel=\"noopener noreferrer\">Process for the production of 1,3-dichloro-2-propanol from glycerin and hydrochloric acid in the presence of organic carboxylic acid catalysts.\u00a0<\/a><\/b>Siano, Dante; Santacesaria, Elio; Fiandra, Valeria; Tesser, Riccardo; Di Nuzzi, Giovanni; Di Serio, Martino; Nastasi, Mario. (Aser S.r.l., Italy). PCT Int. Appl. (2006), WO 2006111810 (A2)<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>EPICHLOROHYDRIN PRODUCTION Biodiesel is a mixture of fatty acids methyl esters (FAMEs) obtained by transesterification of triglycerides (oils or fats) with methanol: The reaction also produces glycerin (around 10 Kg of glycerin per 100 Kg of biodiesel). The strong increase in biodiesel production (from 2 million ton in 2004 to 16 million ton in 2009) [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":107,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[14],"tags":[],"class_list":["post-103","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-subprocesses"],"acf":[],"_links":{"self":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/103","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/comments?post=103"}],"version-history":[{"count":14,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/103\/revisions"}],"predecessor-version":[{"id":658,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/posts\/103\/revisions\/658"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media\/107"}],"wp:attachment":[{"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/media?parent=103"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/categories?post=103"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/nicl.it\/new\/wp-json\/wp\/v2\/tags?post=103"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}